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Cambridge AS & A Level Chemistry

15.1Halogenoalkanes

Halogenoalkanes in Cambridge AS & A Level Chemistry: what the syllabus expects you to know, the learning objectives and how to practise.
Subtopic48 practice questions2 lessons

Learning objectives

What the syllabus expects you to be able to do.

  1. 15.1.1Recall how halogenoalkanes are produced from alkanes, alkenes and alcohols.
  2. 15.1.2Classify halogenoalkanes as primary, secondary or tertiary.
  3. 15.1.3Describe nucleophilic substitution with NaOH(aq), KCN in ethanol, NH₃ in ethanol and aqueous silver nitrate in ethanol.
  4. 15.1.4Describe elimination with NaOH in ethanol.
  5. 15.1.5Describe the SN1 and SN2 mechanisms, including inductive effects of alkyl groups.
  6. 15.1.6Recall that primary halogenoalkanes tend to react by SN2, tertiary by SN1 and secondary by both.
  7. 15.1.7Explain the different reactivities of halogenoalkanes by C–X bond strength.

Lessons

  • Halogenoalkanes: preparation and reactions

    50 min

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  • Nucleophilic substitution: SN1 and SN2 mechanisms

    45 min

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Sample question

A sample question on this topic. Answer it, check it, then read the worked answer.

Halogenoalkanes: sample question

1 mark

An iodoalkane is warmed with aqueous silver nitrate dissolved in ethanol. What is seen?

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Turn Halogenoalkanes into a strength.

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