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Cambridge AS & A Level Chemistry

22.2Mass spectrometry

Mass spectrometry in Cambridge AS & A Level Chemistry: what the syllabus expects you to know, the learning objectives and how to practise.
Subtopic23 practice questions1 lesson

Learning objectives

What the syllabus expects you to be able to do.

  1. 22.2.1Analyse mass spectra in terms of m/e values and isotopic abundances.
  2. 22.2.2Calculate relative atomic mass from isotopic abundances or a mass spectrum.
  3. 22.2.3Deduce molecular mass from the molecular ion peak.
  4. 22.2.4Suggest the identity of simple fragments.
  5. 22.2.5Deduce the number of carbon atoms from the [M+1]⁺ peak.
  6. 22.2.6Deduce the presence of bromine and chlorine from the [M+2]⁺ peak.

Lessons

  • Interpreting mass spectra

    45 min

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Sample question

A sample question on this topic. Answer it, check it, then read the worked answer.

Mass spectrometry: sample question

1 mark

The mass spectrum of propanone, CH₃COCH₃, has its base peak at m/e 43. Which ion causes it?

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