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Cambridge AS & A Level Chemistry

24.2Standard electrode potentials E⦵, standard cell potentials E⦵cell and the Nernst equation

Standard electrode potentials E⦵, standard cell potentials E⦵cell and the Nernst equation in Cambridge AS & A Level Chemistry: what the syllabus expects you to know, the learning objectives and how to practise.
Subtopic44 practice questions2 lessons

Learning objectives

What the syllabus expects you to be able to do.

  1. 24.2.1Define standard electrode (reduction) potential and standard cell potential.
  2. 24.2.2Describe the standard hydrogen electrode.
  3. 24.2.3Describe how to measure E⦵ for metals and non-metals with their ions and for ions of the same element.
  4. 24.2.4Calculate E⦵cell from two electrode potentials.
  5. 24.2.5Use E⦵cell to deduce electrode polarity and electron flow, and to predict feasibility.
  6. 24.2.6Deduce the relative strength of oxidising and reducing agents from E⦵ values.
  7. 24.2.7Construct redox equations from half-equations.
  8. 24.2.8Predict qualitatively how E changes with ion concentrations.
  9. 24.2.9Use the Nernst equation to predict E quantitatively.
  10. 24.2.10Use ΔG⦵ = −nE⦵cellF.

Lessons

  • Standard electrode potentials and cell potentials

    50 min

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  • The Nernst equation and ΔG = −nFE

    40 min

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Sample question

A sample question on this topic. Answer it, check it, then read the worked answer.

Standard electrode potentials E⦵, standard cell potentials E⦵cell and the Nernst equation: sample question

1 mark

Why is a platinum electrode used in the half-cell FeX3+(aq)+eX−⇌FeX2+(aq)\ce{Fe^3+(aq) + e- <=> Fe^2+(aq)}?

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Turn Standard electrode potentials E⦵, standard cell potentials E⦵cell and the Nernst equation into a strength.

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